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According to valence bond theory, which of the following molecules involves sp2 hybridization of orbitals on the central atom? (central atom is bold)


A) C2H2
B) C2H4
C) C2H6
D) CO2
E) H2O

F) B) and D)
G) None of the above

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Valence bond theory predicts that carbon will use _____ hybrid orbitals in the carbonate anion, CO32-.


A) sp
B) sp2
C) sp3
D) sp3d
E) sp3d2

F) A) and E)
G) D) and E)

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A molecule with the formula AX3 uses __________ to form its bonds.


A) sp hybrid orbitals
B) sp2 hybrid orbitals
C) sp3 hybrid orbitals
D) sp3d hybrid orbitals
E) sp3d2 hybrid orbitals

F) All of the above
G) A) and B)

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Determine the shape (geometry) of PCl3 and then decide on the appropriate hybridization of phosphorus in this molecule. (Phosphorus is the central atom.)


A) sp3
B) sp2
C) sp
D) sp3d
E) sp3d 2

F) D) and E)
G) All of the above

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A molecule with the formula AX4 uses _________ to form its bonds.


A) sp hybrid orbitals
B) sp2 hybrid orbitals
C) sp3 hybrid orbitals
D) sp3d hybrid orbitals
E) sp3d2 hybrid orbitals

F) A) and E)
G) A) and B)

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Overlap of two sp2 hybrid orbitals produces a bond.

A) True
B) False

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Valence bond theory explains the bonding in diatomic molecules such as HCl without resorting to the use of hybrid orbitals.

A) True
B) False

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According to the molecular orbital (MO) treatment of the NO molecule, what are the bond order and the number of unpaired electrons, respectively?


A) 2, 2
B) 3, 3
C) 1, 1
D) 1.5, 2
E) 2.5, 1

F) B) and D)
G) A) and B)

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According to valence bond theory, the triple bond in ethyne (acetylene, C2H2) consists of


A) three bonds and no bonds.
B) two bonds and one bond.
C) one bond and two bonds.
D) no bonds and three bonds.
E) none of the above.

F) A) and B)
G) A) and C)

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Valence bond theory predicts that iodine will use _____ hybrid orbitals in ICl2-.


A) sp2
B) sp3
C) sp3d
D) sp3d 2
E) none of the above

F) A) and D)
G) B) and D)

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How many sigma and pi bonds, respectively, are in the molecule below? CH3CH2CHCHCH3?


A) 16, 1
B) 16, 0
C) 15, 1
D) 15, 0
E) 14, 1

F) B) and E)
G) A) and E)

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In one sentence state the basic principle of valence bond theory.

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A covalent bond forms when the...

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Valence bond theory predicts that sulfur will use _____ hybrid orbitals in sulfur dioxide, SO2.


A) sp
B) sp2
C) sp3
D) sp3d
E) sp3d2

F) A) and E)
G) A) and C)

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According to molecular orbital (MO) theory, the twelve outermost electrons in the O2 molecule are distributed as follows:


A) 12 in bonding MOs, 0 in antibonding MOs.
B) 10 in bonding MOs, 2 in antibonding MOs.
C) 9 in bonding MOs, 3 in antibonding MOs.
D) 8 in bonding MOs, 4 in antibonding MOs.
E) 7 in bonding MOs, 5 in antibonding MOs.

F) A) and E)
G) B) and E)

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A carbon-carbon triple bond in a molecule may give rise to the existence of cis and trans isomers.

A) True
B) False

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Which one of the following statements about orbital hybridization is incorrect?


A) The carbon atom in CH4 is sp3 hybridized.
B) The carbon atom in CO2 is sp hybridized.
C) The nitrogen atom in NH3 is sp2 hybridized.
D) sp2 hybrid orbitals are coplanar, and at 120° to each other.
E) sp hybrid orbitals lie at 180° to each other.

F) None of the above
G) A) and B)

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Valence bond theory predicts that bromine will use _____ hybrid orbitals in BrF5.


A) sp2
B) sp3
C) sp3d
D) sp3d 2
E) none of the above

F) A) and C)
G) B) and C)

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In molecular orbital theory, combination of two atomic orbitals produces two molecular orbitals.

A) True
B) False

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