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In the quantum mechanical treatment of the hydrogen atom, the probability of finding an electron at any point is proportional to the wave function Ψ.

A) True
B) False

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Which scientist first proposed that particles of matter could have wave properties?


A) Einstein
B) Planck
C) de Broglie
D) Compton
E) Heisenberg

F) A) and B)
G) B) and E)

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Continuous spectra are characteristic of heated solids.

A) True
B) False

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What type of spectrum, if any, would be produced if the light radiated by a heated atomic gas were to be dispersed through a prism?


A) A continuous band of color
B) A continuous band of color with some dark lines (missing wavelengths)
C) Only blue light
D) Only red light
E) Discrete lines of different colors

F) A) and B)
G) A) and C)

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Which of the following is a correct set of quantum numbers for an electron in a 3d orbital?


A) n = 3, l = 0, ml = −1
B) n = 3, l = 1, ml = +3
C) n = 3, l = 2, ml = 3
D) n = 3, l = 3, ml = +2
E) n = 3, l = 2, ml = −2

F) A) and D)
G) None of the above

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Atomic orbitals developed using quantum mechanics


A) describe regions of space in which one is most likely to find an electron.
B) describe exact paths for electron motion.
C) give a description of the atomic structure which is essentially the same as the Bohr model.
D) allow scientists to calculate an exact volume for the hydrogen atom.
E) are in conflict with the Heisenberg Uncertainty Principle.

F) A) and B)
G) B) and C)

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The orientation in space of an atomic orbital is associated with


A) the principal quantum number ( n) .
B) the angular momentum quantum number ( l) .
C) the magnetic quantum number ( ml) .
D) the spin quantum number ( ms) .
E) None of these choices are correct.

F) None of the above
G) All of the above

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Excited hydrogen atoms radiate energy in the


A) infrared region only.
B) visible region only.
C) ultraviolet region only.
D) visible and ultraviolet regions only.
E) infrared, visible, and ultraviolet regions.

F) C) and E)
G) A) and E)

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In the quantum mechanical treatment of the hydrogen atom, which one of the following combinations of quantum numbers is not allowed? In the quantum mechanical treatment of the hydrogen atom, which one of the following combinations of quantum numbers is not allowed?   A) A B) B C) C D) D E) E


A) A
B) B
C) C
D) D
E) E

F) A) and E)
G) All of the above

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The Rydberg equation is an example of an empirical equation.

A) True
B) False

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Which scientist demonstrated that photons transferred momentum during collisions with matter?


A) Bohr
B) de Broglie
C) Planck
D) Compton
E) Billiard

F) None of the above
G) A) and B)

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Who proposed a model that successfully explained the photoelectric effect?


A) Planck
B) Einstein
C) Compton
D) Rydberg
E) Bohr

F) C) and E)
G) B) and D)

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Which word best describes the phenomenon which gives rise to a rainbow?


A) Reflection
B) Dispersion
C) Diffraction
D) Interference
E) Deflection

F) A) and E)
G) All of the above

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Interference of light waves


A) separates light into its component colors.
B) creates a pattern of light and dark regions.
C) focuses a broad beam of light into a point.
D) bends light as it passes the edge of an object.
E) creates a laser beam.

F) C) and E)
G) B) and C)

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Who developed an empirical equation from which the wavelengths of lines in the spectrum of hydrogen atoms can be calculated?


A) Planck
B) de Broglie
C) Bohr
D) Rutherford
E) Rydberg

F) B) and E)
G) A) and B)

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Green light has a wavelength of 5200 Å. Calculate the energy of one photon of green light.


A) 3.4 × 10 40 J
B) 3.4 × 10 30 J
C) 3.8 × 10 29 J
D) 3.4 × 10 27 J
E) 3.8 × 10 19 J

F) B) and D)
G) D) and E)

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Continuous spectra are characteristic of molecules in the gas phase.

A) True
B) False

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Consider the following adjectives used to describe types of spectrum: continuous, line, atomic, emission and absorption.How many of them are appropriate to describe the spectrum of radiation given off by a black body?


A) None
B) One
C) Two
D) Three
E) Four

F) C) and E)
G) A) and D)

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Platinum, which is widely used as a catalyst, has a work functionΦ (the minimum energy needed to eject an electron from the metal surface) of 9.05 × 1019 J. What is the longest wavelength of light which will cause electrons to be emitted?


A) 2.196 × 10 7 m
B) 4.553 × 10 6 m
C) 5.654 × 10 2 m
D) 1.370 × 10 15 m
E) > 10 6 m

F) All of the above
G) A) and D)

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The Rydberg equation, giving the wavelengths of lines in the spectrum of the hydrogen atom, was obtained by assuming that energy is quantized.

A) True
B) False

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